If there is adequate legal reasons that they cannot live together anymore in harmony as husband and wife, the husband can submit divorce application, *while* the wife can file a complaint to the Court.
Answers:
In my opinion it should be:
If there "ARE" adequate legal resons that they cannot live together anymore in harmony as husband and wife, the husband can submit a divorce application, "WHILE/OR" the wife can file a complaint to the court.
The reason the word while sounds awkward is that you have a huge run-on sentence. It can be used in that way, but I would simply separate the second thought (the wife can file . . . ) into a separate sentence. Just my opinion.
Good luck.
PS it would be "If there are legal reasons . . . "(I would take out adequate also, using the term legal implies that they are adequate so that would be redundant). Again, Just my opinion.
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